Lab-grown diamonds: HPHT and CVD
Diamond is grown by two routes. High-pressure, high-temperature (HPHT) growth imitates conditions in the mantle. Carbon and a small diamond seed sit in a molten metal solvent, usually iron, nickel or cobalt, inside a belt, cubic or split-sphere press. Gem growth runs at about 5–6 GPa and 1,300–1,600 °C. At General Electric, Tracy Hall reached a reproducible synthesis on December 16, 1954, using a belt press with graphite and an iron sulfide catalyst at roughly 7 GPa and 1,600 °C, and the team published in Nature in 1955. Researchers at the Swedish company ASEA had made diamond in 1953 but did not report it at the time, and credit for the first synthesis is still argued over. Herbert Strong and Robert Wentorf of General Electric went on to grow gem-quality crystals up to 6 mm across over several days.
Chemical vapor deposition (CVD) builds diamond from gas. Hydrogen with a small fraction of a hydrocarbon, generally under 10% methane, is energized into a plasma at roughly 20–500 mbar, and carbon settles layer by layer on seed plates held at 600–1,200 °C. CVD crystals often grow brownish and are frequently given post-growth HPHT treatment.
Both routes yield real diamond. Since July 2019 GIA has issued a Laboratory-Grown Diamond Report that names the growth method.